Hi there Giddy Up.
Considering the little experience I read you have, you have bought one hell of a kit there. You'll have lots of fun with it!!
The thing is mate, tuning and head selection is a craft in itself and just as paradiddles and Jazz independence, will require practice and experimentation. The kit will always have it's inner sound despite the heads you choose. But your head choice will colour that sound, and so will your tuning too. It depends on what you want to hear and feel from the kit.
For now maybe slap on Remo Coated Ambassadors top and bottom on the Toms, that will keep things equal both sides of the Drum so you can experiment in a balanced way. Also good for getting an older style sound. The Bass drum I would suggest maybe a Powerstroke(Coated or Clear) on the Batter side and a simple Coated Ambassador on the Front.
Snare should be Coated Ambassador Batter and clear Ambassador Snare head on the Bottom.
Thats a good STARTING POINT. You can then start to play with Emperors or even Pinstrips for that matter on the Batters. Fyberskyns will totally darken the sound which can be so cool if you like that sort of thing. Fitting out with thin Diplomats will totally change things again.
Now thats talking Remo. Then there are the other makers such as Aquarian and Evans. They bring other colours to your kit that some drummers prefer. Evans have a different coating on there heads to Remo. I find that some of my Snares sound better with Aquarian heads on but not others. Apparently DW Toms are the Bomb with Evans Heads.
Mate you will have to spend hours and hours tinkering with tuning. Your going to have to experiment with head selection to learn what those 69 Rogers can do. But for me that's always been part of the fun.
I hope that helps.